S. Okamoto et al., Orbital structure and magnetic ordering in layered manganites: Universal correlation and its mechanism - art. no. 104401, PHYS REV B, 6310(10), 2001, pp. 4401
Correlation between orbital structure and magnetic ordering in layered mang
anites is examined. A level separation between the 3d(3z2-r2) and 3d(x2-y2)
orbitals in a Mn ion is calculated in the ionic model for a large number o
f the compounds. It is found that the relative stability of the orbitals do
minates the magnetic transition temperatures as well as the magnetic struct
ures at zero temperature. A mechanism of the correlation between orbital an
d magnetism is explained by a theory based on the model with the two Eg orb
itals under strong electron correlation.