Practical approach for catalytic asymmetric allylation of aldehydes with achiral bidentate titanium(IV) complex

Authors
Kii, S Maruoka, K
Citation
S. Kii et K. Maruoka, Practical approach for catalytic asymmetric allylation of aldehydes with achiral bidentate titanium(IV) complex, TETRAHEDR L, 42(10), 2001, pp. 1935-1939
Citations number
71
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
10
Year of publication
2001
Pages
1935 - 1939
Database
ISI
SICI code
0040-4039(20010304)42:10<1935:PAFCAA>2.0.ZU;2-1
Abstract
A new, chiral bidentate Ti(IV) complex of type 1 was successfully designed and can be utilized for simultaneous coordination to aldehyde carbonyls, th ereby allowing the precise enantioface discrimination of such carbonyls for a new catalytic, practical enantioselective allylation of aldehydes with a llyltributyltin. (C) 2001 Elsevier Science Ltd. All rights reserved.