Thin film transistors and solar cells from polycrystalline silicon suffer f
rom the influence of grain boundary charges. This contribution reviews thre
e possibilities to suppress these charges: (i) by the selection of speciall
y oriented grain boundaries in small-grained silicon. Analysis of solar cel
ls demonstrates that (110)-textured films must contain electrically low-act
ive boundaries. (ii) Special laser crystallization yields large-grained Si
of excellent quality. (iii) Transfer techniques allow one to fabricate sing
le crystal films on foreign substrates. In addition to these three methods,
we discuss joined-wafer silicon for growth of single crystalline Si films
and layers of essentially unlimited size. (C) 2001 Elsevier Science B.V. Al
l rights reserved.