A simple, selective and sensitive fluorometric method is presented for
the determination of formaldehyde in water based on its reaction with
3,4-diaminoanisole in alkaline ethanol-water solution to give a stron
gly fluorescing Schiff base. The dependence of the fluorescence intens
ity on the solvent composition, quenching by acetic and sulphuric acid
, heating time and interference by other compounds is discussed. The d
etection limit of the method is 0.6 mu g/L. The recovery of formaldehy
de spiked into river water is 93% with an R.S.D of 6.05% at a concentr
ation level of 10 mu g/L.