In this work, we present a study of the behavior of linewidths of excitonic
photoluminescence transitions measured at 10 K in AlGaN alloys as a functi
on of Al concentration. Samples we have investigated are grown by low-press
ure metalorganic chemical vapor deposition on (0001) oriented sapphire subs
trates with low-temperature GaN buffer layers. The Al composition ranged fr
om 0%-35%. We find that the values of the excitonic linewidth increase as a
function of Al concentration and agree very well with those calculated usi
ng a model in which the broadening effect is assumed to be due to compositi
onal disorder in semiconductor alloys. The values of the excitonic linewidt
hs measured in our samples are considerably smaller than those reported rec
ently, thus attesting to the high quality of our samples. (C) 2001 American
Institute of Physics.