The role of calcium hydroxide in processes affecting the durability of conc
rete exposed to aggressive media was examined. Compacted calcium hydroxide
specimens were immersed in various solutions: including MgCl2 and MySO(4) a
nd length changes were continuously monitored. The view that the formation
of crystalline phases in cement systems is in itself not an a priori condit
ion for expansion is discussed. Evidence for a dissolution/precipitation-ba
sed expansive mechanism is presented. (C) 2001 Elsevier Science Ltd. All ri
ghts reserved.