Rb. Yahya et al., Hydrothermal synthesis of potassium hexatitanates under subcritical and supercritical water conditions and its application in photocatalysis, CHEM MATER, 13(3), 2001, pp. 842-847
Hydrothermal synthesis of potassium hexatitanate was carried out under vari
ous subcritical and supercritical water conditions using potassium hydroxid
e and titanium tetraisopropoxide as starting materials. Characterization of
these hydrothermally synthesized potassium hexatitanates by XRD, SEM, TEM,
and thermal analysis showed that long, felted-like fibers of potassium hex
atitanates were formed and these fibers are thermally stable up to 1273 K.
The use of these fibers as photocatalysts in water decomposition was invest
igated using ruthenium oxide as the catalytic active phase. Photocatalytic
activity in the water decomposition reaction was found to be much higher in
comparison with the solid state synthesized photocatalyst. Activites of mo
re than 13-fold were obtained for the photocatalysts synthesized under subc
ritical water conditions and between 27- and 59-fold for those synthesized
under supercritical water conditions for water decomposition.