P. Becker et C. Wickleder, Crystal growth and spectroscopic characterisation of BiB3O6 : RE3+ (RE3+ =Pr3+, Nd3+, Gd3+, Er3+, Tm3+), CRYST RES T, 36(1), 2001, pp. 27-37
Large single crystals of optical duality of BiB3O6:RE3+ with RE3+ = Pr3+, N
d3+, Gd3+, Er3+ and Tm3+ were grown from nearly stoichiometric melts using
the top-seeding growth technique to dimensions up to 12 x 12 x 18 mm(3). Ab
sorption spectra were measured in the wavelength range from 10000 cm(-1) to
30000 cm(-1) with an absorption spectrometer to estimate the doping concen
tration of RE3+. For the determination of the phonon energies and the quenc
hing behaviour of the host lattice IR and Raman spectra were recorded.