Effect of urea on metastable zone width, induction time and nucleation parameters of ammonium dihydrogen orthophosphate

Citation
Np. Rajesh et al., Effect of urea on metastable zone width, induction time and nucleation parameters of ammonium dihydrogen orthophosphate, CRYST RES T, 36(1), 2001, pp. 55-63
Citations number
16
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CRYSTAL RESEARCH AND TECHNOLOGY
ISSN journal
02321300 → ACNP
Volume
36
Issue
1
Year of publication
2001
Pages
55 - 63
Database
ISI
SICI code
0232-1300(2001)36:1<55:EOUOMZ>2.0.ZU;2-7
Abstract
Enhancement of the metastable zone width in ammonium dihydrogen ortho phosp hate (ADP) was achieved by the addition of the organic compound Urea to ADP solution. The metastable zone width studies were carried out for various t emperature cooling rates and the nucleation parameters are studied. The ind uction period was studied and the critical nucleation parameters calculated based on classical theory for homogeneous nucleation are discussed. The cr itical nucleation parameters increase with the increase in concentration of doping.