Trimethylchlorosilane/acetyl chloride induced metal mediated chemoselective chlorination of 16-dehydro-20-oxopregnanes

Citation
S. Hazarika et Pk. Chowdhury, Trimethylchlorosilane/acetyl chloride induced metal mediated chemoselective chlorination of 16-dehydro-20-oxopregnanes, I J CHEM B, 40(2), 2001, pp. 145-147
Citations number
8
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY
ISSN journal
03764699 → ACNP
Volume
40
Issue
2
Year of publication
2001
Pages
145 - 147
Database
ISI
SICI code
0376-4699(200102)40:2<145:TCIMMC>2.0.ZU;2-N
Abstract
Chemoselective chlorination of 16-dehydropregne-nolone acetate (16-DPA) thr ough in situ generation of MnCl4 from a system consisting of MnO2-TMSCl/AcC l has been described.