HIGH-RESOLUTION CARS SPECTROSCOPY OF SMALL CARBON-DIOXIDE CLUSTERS - INVESTIGATION OF THE CO2 DIMER IN THE NU(1) 2-NU(2) FERMI DYAD/

Authors
HUISKEN F RAMONAT L SANTOS J SMIRNOV VV STELMAKH OM VIGASIN AA
Citation
F. Huisken et al., HIGH-RESOLUTION CARS SPECTROSCOPY OF SMALL CARBON-DIOXIDE CLUSTERS - INVESTIGATION OF THE CO2 DIMER IN THE NU(1) 2-NU(2) FERMI DYAD/, Journal of molecular structure, 410, 1997, pp. 47-50
Citations number
8
Categorie Soggetti
Chemistry Physical
Journal title
Journal of molecular structure → ACNP
ISSN journal
00222860
Volume
410
Year of publication
1997
Pages
47 - 50
Database
ISI
SICI code
0022-2860(1997)410:<47:HCSOSC>2.0.ZU;2-W
Abstract
High-resolution CARS spectroscopy has been employed to study the forma tion of small carbon dioxide clusters in a supersonic jet near the low er frequency component of the nu(1)/2 nu(2) Fermi dyad at 1285.41 cm(- 1). A pronounced structure was found at 1284.73 cm(-1), redshifted by 0.68 cm(-1) from the monomer Q-branch. Analysis of the complete set of experimental data and comparison with kinetic calculations indicate t hat the new feature must be attributed to the CO2 dimer. (C) 1997 Else vier Science B.V.