Synthesis and characterization of poly(hydroxyether). I. Poly(hydroxyether) based on 2,2-bis(4-hydroxyphenyl)hexafluoropropane and 2,2-bis(4-hydroxyphenyl)propane
T. Fukuoka et al., Synthesis and characterization of poly(hydroxyether). I. Poly(hydroxyether) based on 2,2-bis(4-hydroxyphenyl)hexafluoropropane and 2,2-bis(4-hydroxyphenyl)propane, J APPL POLY, 80(10), 2001, pp. 1687-1696
Linear poly(hydroxyethers) (PHEs) were prepared by the base-induced condens
ation of bisphenols with epichlorohydrin in a polar mixed solvent. The bisp
henols used were 2,2-bis(4-hydroxyphenyl)propane (bisphenol A) and 2,2-bis(
4-hydroxyphenyl)-hexafluoropropane (bisphenol AF). Bisphenol A-based homo-P
HE (HPHE-A), bisphenol AF-based homo-PHE (HPHE-AF), and copoly(hydroxyether
s) (CPHEs) based on both the bisphenols with various compositions were char
acterized in terms of chemical structure, thermal property, solubility, and
contact angle. The incorporation of bisphenol AF unit into HPHE-A brought
about the increases in the glass-transition temperature, the solubility in
organic solvents, and the hydrophobicity. The sequence of the repeating uni
t in the copolymer was analyzed by H-1-NMR and the result agreed well with
the one calculated as a random copolymer. (C) 2001 John Wiley & Sons, Inc.
J Appl Polym Sci 80: 1687-1696, 2001.