Experimental excess enthalpies for the following seven systems have been de
termined with the help of isothermal flow calorimetry: benzene + cyclohexan
e at 50, 90, and 140 degreesC, heptane + diethyl carbonate at 100 and 140 d
egreesC, hexane + dimethyl carbonate at 90 degreesC, dimethyl carbonate + h
eptane at 90 and 140 degreesC, perfluoro-2-methylpentane + benzene at 50, 9
0, and 140 degreesC, 1,2-epoxybutane + methanol at 90 and 140 degreesC, and
1,2-expoxybutane + 2-ethyl-1-hexanol at 90 and 140 degreesC. The experimen
tal H-E values have been used for the revision and extension of the group c
ontribution method Modified UNIFAC (Dortmund). The predicted results are in
good agreement with the experimental data.