During previous Joint European Torus (JET) deuterium-to-tritium change-over
experiments, subdivertor tritium concentrations were compared with those m
easured at the strike point region and found to differ significantly during
the first few discharges, which was correlated with wall saturation. New d
euterium-to-hydrogen fueling experiments in JET have been made and are comp
ared to these previous experiments. Rates of hydrogenic species exchange ar
e similar to those found in previous tritium experiments. granting differen
ces in divertor configuration and mass ratio. In the new experiments, measu
rements of the CD and CH molecular band intensities near the divertor strik
e point monitor an intermediate stage of particle exchange between the plas
ma and wall. The CD/CH ratio correlates well with both the plasma and subdi
vertor concentration. The neutral transport code EIRENE and the wall hydrog
en trapping and diffusion code WDIFFUSE have been used to evaluate the wall
saturation. It appears that chemically-related processes play a role in me
diating the plasma-wall exchange. (C) 2001 Elsevier Science B.V. All rights
reserved.