Very large neutral and polyanionic Fe/Au cluster-containing dendrimers

Authors
Benito, M Rossell, O Seco, M Segales, G Maraval, V Laurent, R Caminade, AM Majoral, JP
Citation
M. Benito et al., Very large neutral and polyanionic Fe/Au cluster-containing dendrimers, J ORGMET CH, 622(1-2), 2001, pp. 33-37
Citations number
23
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
622
Issue
1-2
Year of publication
2001
Pages
33 - 37
Database
ISI
SICI code
0022-328X(20010315)622:1-2<33:VLNAPF>2.0.ZU;2-P
Abstract
Treatment of tetrahydrofuran solutions of a series of ClAu-terminated dendr imers with the iron anions [Fe-2(CO)(7)(PPh2)](-) and Fe-3(CO)(11)](2-) has allowed the new dendrimer species decorated on the surface by Fe2Au or Fe2 Au units to be isolated, including one having up to 192 Fe2Au clusters. (C) 2001 Elsevier Science B.V. All rights reserved.