The synthesis and structure of the thiosulfonato iron complexes CpFe(CO)(2)SS(O)(2)R

Authors
El-khateeb, M Shaver, A Lebuis, AM
Citation
M. El-khateeb et al., The synthesis and structure of the thiosulfonato iron complexes CpFe(CO)(2)SS(O)(2)R, J ORGMET CH, 622(1-2), 2001, pp. 293-296
Citations number
30
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
622
Issue
1-2
Year of publication
2001
Pages
293 - 296
Database
ISI
SICI code
0022-328X(20010315)622:1-2<293:TSASOT>2.0.ZU;2-5
Abstract
Treatment of the iron polysulfanes (mu -S-x)[CpFe(CO)(2)](2) (x = 3, 4) wit h sulfonyl chlorides RSO2Cl (R = CF3 (1), CCl3 (2), C6F5 (3)) gave the corr esponding iron thiosulfonato complexes CpFe(CO)(2)SS(O)(2)R in good yields. Crystal structure for 2: P(2)1/c, a = 6.704(2), b = 8.933(2), c = 22.603(5 ) Angstrom, alpha = 90, beta = 92.82(2), gamma = 90 degrees, V = 1352.0(6) Angstrom (3) and Z = 4. (C) 2001 Elsevier Science B.V. All rights reserved.