A theoretical model is presented of the thermophoresis of latex particles i
n polar solvents. Expressions for the thermophoretic mobility (TM) of the p
articles, which consist of polymer solutions emulsified in a poor solvent w
ith the addition of salt, are obtained. The model is based on the thermopho
resis of polymer chains partitioned between the emulsion droplet and the su
rrounding solvent. The partitioning is assumed to originate with the "salti
ng in" of monomer units (mers) in the surfactant film that surrounds and st
abilizes the latex particle. Correlation between mers then leads to a parti
tioning of mers between the good solvent inside the latex particle and the
surrounding poor solvent. Assuming a mer concentration th;tt decays exponen
tially into the surrounding solvent, the expression for the particle TM is
obtained. It is found that, with the increase of the square of the derived
dimensionless parameter, the latex particle TM increases from zero to a hyp
othetical value of the polymer's TM in the poor solvent. The dimensionless
parameter contains the product of mer concentration at the particle surface
, the mer radius, and the square of the mean thickness of the mer distribut
ion in the external solvent. Based on experimental data, the dimensionless
parameter has a value greater than or equal to unity for polystyrene in the
polar solvents water and acetonitrile. The TM of polystyrene in these syst
ems is comparable with that of polystyrene in nonpolar solvents.