In this paper we investigate the time-resolved and stationary photoluminesc
ence (PL) Of silicon nanocrystals fabricated in a silicon oxide matrix. The
PL intensity reveals a nonexponential decay for all temperatures which can
be fitted by a ''stretch'' -exponential function. From 60 down to 5 K an i
ncrease of decay time is observed going along with a decrease of the PL int
ensity. In addition the PL spectra show a shape change during the decay. Th
e experimental data are interpreted in the model of self-trapped excitons (
STE) which are localized in a Si-Si dimer. A numerical simulation of this m
odel provides the radiative and nonradiative recombination times of the STE
transition, the energy of the STE singlet-triplet splitting and the height
of the self-trapped barrier.