Through permanganate measurements, this study demonstrates a simple, rapid,
practical, and direct spectrophotometric pulp kappa test method through on
e calibration with a standard pulp sample of known kappa number. Two perman
ganate absorption measurements were made in both the testing and standard p
ulp-permanganate reacting solutions for kappa calculation, one at the begin
ning of the reaction and the other at about 2-3 min into the reaction. The
measured kappa numbers of 13 blended hardwood pulps and another 45 pulps fr
om laboratory pulping of 10 hardwood and softwood species in a kappa number
range of 10-70 are reported. The results showed excellent agreement with t
hose obtained by the standard TAPPI kappa method. The effect of the pulp-pe
rmanganate reaction temperature on measured kappa number using the present
method is also presented. The method has the potential for on-line kappa mo
nitoring in pulp production.