The mechanism of formation of copper aluminide in the thermal explosion mode

Citation
Eb. Pis'Menskaya et al., The mechanism of formation of copper aluminide in the thermal explosion mode, RUSS CHEM B, 49(12), 2000, pp. 1954-1959
Citations number
7
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
49
Issue
12
Year of publication
2000
Pages
1954 - 1959
Database
ISI
SICI code
1066-5285(200012)49:12<1954:TMOFOC>2.0.ZU;2-X
Abstract
The mechanism of formation of copper aluminides in the thermal explosion mo de was studied. A molded mixture of copper and aluminum powders was heated to the self-ignition temperature by the radiation of a tungsten heater. The phase transformations were detected by time-resolved X-ray diffraction (TR XRD). The kinetics of heat release due to the chemical reaction was studied by measuring the temperature of the sample. The macrokinetic stages of the process were revealed, and the apparent activation energy of each stage wa s estimated.