2-polyfluoroalkylchromones 5. Nitration and chlorination of 2-trifluoromethylchromones

Citation
Vy. Sosnovskikh et Bi. Usachev, 2-polyfluoroalkylchromones 5. Nitration and chlorination of 2-trifluoromethylchromones, RUSS CHEM B, 49(12), 2000, pp. 2074-2076
Citations number
13
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
49
Issue
12
Year of publication
2000
Pages
2074 - 2076
Database
ISI
SICI code
1066-5285(200012)49:12<2074:25NACO>2.0.ZU;2-T
Abstract
Electrophilic nitration of 2-trifluoromethylchromone and its 6- and 7-metho xy derivatives affords 6-, 5-, and 8-nitro derivatives, respectively, while 5,7-dimethyl-2-trifluoromethylchromone yields a 6,8-dinitro derivative. Ra dical chlorination results in 3-chloro derivatives.