New stable reagents for the nucleophilic trifluoromethylation. Part 4: Trifluoromethylation of disulfides and diselenides with hemiaminals of trifluoroacetaldehyde

Citation
G. Blond et al., New stable reagents for the nucleophilic trifluoromethylation. Part 4: Trifluoromethylation of disulfides and diselenides with hemiaminals of trifluoroacetaldehyde, TETRAHEDR L, 42(13), 2001, pp. 2473-2475
Citations number
18
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
13
Year of publication
2001
Pages
2473 - 2475
Database
ISI
SICI code
0040-4039(20010326)42:13<2473:NSRFTN>2.0.ZU;2-U
Abstract
Hemiaminals of fluoral and derivatives have been previously described as ef ficient new reagents for the nucleophilic trifluoromethylation of carbonyl compounds. Their use has been extended to the synthesis of trifluoromethyl sulfides and selenides from disulfides and diselenides. (C) 2001 Elsevier S cience Ltd. All rights reserved.