Highly regioselective iodoperfluoroalkylation of allenes with perfluoroalkyl iodides upon irradiation with near-UV light

Citation
A. Ogawa et al., Highly regioselective iodoperfluoroalkylation of allenes with perfluoroalkyl iodides upon irradiation with near-UV light, TETRAHEDR L, 42(13), 2001, pp. 2489-2492
Citations number
10
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
13
Year of publication
2001
Pages
2489 - 2492
Database
ISI
SICI code
0040-4039(20010326)42:13<2489:HRIOAW>2.0.ZU;2-4
Abstract
Upon irradiation through Pyrex with a xenon lamp (hv>300 nm), perfluoroalky l iodides add to terminal allenes regioselectively to afford the correspond ing iodoperfluoroalkylated products, where perfluoroalkyl and iodo groups a re selectively introduced into the terminal and central carbons of allenes, respectively. (C) 2001 Elsevier Science Ltd. All rights reserved.