ON THE SYSTEMATICS OF PHASE-EQUILIBRIA IN COMPLEX MAGNESIUM RARE-EARTH SYSTEMS - GD-Y-MG SYSTEM

Citation
M. Giovannini et al., ON THE SYSTEMATICS OF PHASE-EQUILIBRIA IN COMPLEX MAGNESIUM RARE-EARTH SYSTEMS - GD-Y-MG SYSTEM, Zeitschrift fur Metallkunde, 88(5), 1997, pp. 372-378
Citations number
56
Categorie Soggetti
Metallurgy & Metallurigical Engineering
Journal title
ISSN journal
00443093
Volume
88
Issue
5
Year of publication
1997
Pages
372 - 378
Database
ISI
SICI code
0044-3093(1997)88:5<372:OTSOPI>2.0.ZU;2-6
Abstract
General properties of magnesium alloys with one or two different rare earth metals are briefly summarized and discussed. The regular trends observed in the intermediate phase formation are used to predict the c haracteristics of the room temperature isothermal section of the Gd-Y- Mg system. The partial experimental section at 500 degrees C in the co mposition range approximate to 50 to 100 at.% Mg, has then been determ ined and found to be in fair agreement with the predicted one. The det ermination has been carried out by X-ray powder diffraction, optical a nd scanning electron microscopy and electron probe microanalysis. The following phases have been identified: the continuous solid solution c P2-CsC1 type along the line Gd1-xYxMg and, along the line Gd1-xYxMg2, two Laves-type solid solution fields (cF24-MgCu2 type, GdMg2 based for about 0 less than or equal to x < 0.18 and hP12-MgZn2 type, YMg2 base d for about 0.26 < x less than or equal to 1). The extension into the ternary field, moreover, has been determined for ME and the GdMe3, GdM g5 and Y5Mg24 based phases.