M. Giovannini et al., ON THE SYSTEMATICS OF PHASE-EQUILIBRIA IN COMPLEX MAGNESIUM RARE-EARTH SYSTEMS - GD-Y-MG SYSTEM, Zeitschrift fur Metallkunde, 88(5), 1997, pp. 372-378
General properties of magnesium alloys with one or two different rare
earth metals are briefly summarized and discussed. The regular trends
observed in the intermediate phase formation are used to predict the c
haracteristics of the room temperature isothermal section of the Gd-Y-
Mg system. The partial experimental section at 500 degrees C in the co
mposition range approximate to 50 to 100 at.% Mg, has then been determ
ined and found to be in fair agreement with the predicted one. The det
ermination has been carried out by X-ray powder diffraction, optical a
nd scanning electron microscopy and electron probe microanalysis. The
following phases have been identified: the continuous solid solution c
P2-CsC1 type along the line Gd1-xYxMg and, along the line Gd1-xYxMg2,
two Laves-type solid solution fields (cF24-MgCu2 type, GdMg2 based for
about 0 less than or equal to x < 0.18 and hP12-MgZn2 type, YMg2 base
d for about 0.26 < x less than or equal to 1). The extension into the
ternary field, moreover, has been determined for ME and the GdMe3, GdM
g5 and Y5Mg24 based phases.