Behavioral patterns of heterometallic cuboidal derivatives of [M(3)Q(4)(H2O)(9)](4+) (M = Mo, W; Q = S, Se)

Authors
Hernandez-Molina, R Sokolov, MN Sykes, AG
Citation
R. Hernandez-molina et al., Behavioral patterns of heterometallic cuboidal derivatives of [M(3)Q(4)(H2O)(9)](4+) (M = Mo, W; Q = S, Se), ACC CHEM RE, 34(3), 2001, pp. 223-230
Citations number
37
Categorie Soggetti
Chemistry & Analysis",Chemistry
Journal title
ACCOUNTS OF CHEMICAL RESEARCH
ISSN journal
00014842 → ACNP
Volume
34
Issue
3
Year of publication
2001
Pages
223 - 230
Database
ISI
SICI code
0001-4842(200103)34:3<223:BPOHCD>2.0.ZU;2-Y
Abstract
This Account reports recent progress in the study of some similar to 20 het erometal derivatives of [Mo3S4(H2O)(9)](4+) with reference also to W and Se analogues. Single cubes (3:1) and corner-shared double cubes (6:1), as wel l as dimers of the 3:1 single cubes, are considered. A classification of th e heterometals as subtypes A, B, and C is introduced.