Modular synthesis framework for combined separation/reaction systems

As an extension to our earlier work (1999a), this article presents a system atic approach for the synthesis of combined separation/reaction systems whi ch involves a phenomena-based representation formulated within a superstruc ture optimization framework. A multifunctional, mass-/heat-transfer-based p rocess module is utilized as the building block of process alternatives. Wi thin this module, Gibbs-free-energy-based "driving-force" constraints are i ntroduced to describe the physiochemical phenomena and to ensure feasibilit y of pure separation, reaction or combined separation/reaction (such as rea ctive distillation). A superstructure of these multipurpose modules is then systematically constructed to represent process alternatives, which are no t explicitly pre-postulated, but investigated as mass and heat exchange net work possibilities.