Af. Maslyuk et al., POLYMERIZATION OF THE OKM-2 OLIGOCARBONAT E METHACRYLATE PHOTOSENSITIZED BY OLIGOOXYPROPYLENE GLYCOL BENZOPHENONES, Vysokomolekularnye soedinenia. Seria A, 39(5), 1997, pp. 773-780
Photosensitized bulk polymerization of the OKM-2 oligocarbonate methac
rylate was studied. The proton accepters were represented by oligooxyp
ropylene glycol benzophenones-new oligomeric photosensitizers with oli
goester blocks of various molecular masses and terminal benzophenone f
ragments. It is demonstrated that the parameters of polymerization kin
etics, X-ray diffraction, and strength are determined predominantly by
the ratio of proton acceptor and donor (diethylaniline) concentration
s.