Phosphide coupling in the reaction of Sn(NMe2)(2) with MesPHLi; synthesis and structure of the Sn(II) phosphide dianion [{Sn(mu-PMes)}(2)(MesP)(2)](2-) (Mes=2,4,6-Me3C6H2)

Authors
Bond, AD Rothenberger, A Woods, AD Wright, DS
Citation
Ad. Bond et al., Phosphide coupling in the reaction of Sn(NMe2)(2) with MesPHLi; synthesis and structure of the Sn(II) phosphide dianion [{Sn(mu-PMes)}(2)(MesP)(2)](2-) (Mes=2,4,6-Me3C6H2), CHEM COMMUN, (6), 2001, pp. 525-526
Citations number
15
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
6
Year of publication
2001
Pages
525 - 526
Database
ISI
SICI code
1359-7345(2001):6<525:PCITRO>2.0.ZU;2-N
Abstract
In contrast to the reactions of other primary phosphides with Sn(NMe2)(2), the reaction of MesPHLi with Sn(NMe2)(2) results in partial coupling of Mes P groups in the product (which contains the novel Sn(ii) dianion [{(Sn(mu - PMes)}(2)-(MesP)(2)](2-)).