Extended framework materials incorporating cyanide cluster complexes: structure of the first 3D architecture accommodating organic molecules

Authors
Naumov, NG Soldatov, DV Ripmeester, JA Artemkina, SB Fedorov, VE
Citation
Ng. Naumov et al., Extended framework materials incorporating cyanide cluster complexes: structure of the first 3D architecture accommodating organic molecules, CHEM COMMUN, (6), 2001, pp. 571-572
Citations number
28
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
6
Year of publication
2001
Pages
571 - 572
Database
ISI
SICI code
1359-7345(2001):6<571:EFMICC>2.0.ZU;2-K
Abstract
Hexadentate cluster anions [Re6S8(CN)(6)](4-) coordinate to Mn(ii) centers to give a neutral 3D coordination network topologically related to the stru cture of Prussian Blue; the residual space is filled with isopropyl alcohol molecules, both ligated to Mn(ii) and guest-solvated.