Formation of folded complexes retaining intramolecular H-bonding in the extraction of nickel(II) by phenolic oxime and aliphatic diamine ligands

Authors
Hultgren, VM Atkinson, IM Beddoes, RL Collison, D Garner, CD Helliwell, M Lindoy, LF Tasker, PA
Citation
Vm. Hultgren et al., Formation of folded complexes retaining intramolecular H-bonding in the extraction of nickel(II) by phenolic oxime and aliphatic diamine ligands, CHEM COMMUN, (6), 2001, pp. 573-574
Citations number
15
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
6
Year of publication
2001
Pages
573 - 574
Database
ISI
SICI code
1359-7345(2001):6<573:FOFCRI>2.0.ZU;2-J
Abstract
Solvent extraction of Ni-II by phenolic oximes is enhanced significantly by addition of aliphatic diamines; octahedral [Ni(ii)(phenolate-oxime)(2)(dia mine)] complexes have been characterised that contain a novel folded confor mation, retaining intramolecular hydrogen bonding between the two oxime lig ands.