Recovery of useful hydrocarbons from oil palm waste using ZrO2 supporting FeOOH catalyst

The possibility of recovering useful hydrocarbons from oil palm waste deriv ed lignocellulose (palm shell oil) using steam tolerant catalysts was inves tigated. The examined catalysts were rare earth metal exchanged Y-type (REY ) zeolites, nickel supporting REY zeolites and FeOOH catalysts. It was foun d that palm shell oil could be converted to a mixture which mainly contains phenol, acetone and butanone without hardly generating solid residues when a FeOOH catalyst was used. Therefore, by catalytic reaction, this waste-de rived material may become a new and abundant chemical source. The catalytic activity of this FeOOH catalyst can be enhanced by supporting ZrO2 on it. It was found that oxygen transfer during reaction occurs mainly from H2O to the products, not from the oxygen of the catalyst. It is assumed that the supported ZrO2 plays a role of the decomposition of H2O adsorbed on the cat alyst, yielding active hydrogen and oxygen species, which is also supported by the results of thermal desorption spectra and Mossbauer spectroscopy an alysis of the catalyst. (C) 2001 Elsevier Science Ltd. All rights reserved.