Total synthesis of two neolignans for (+/-)-Eusiderin E and (+/-)-Eusiderin F

Authors
Jing, XB Gu, WX Bie, PY Ren, XF Pan, XF
Citation
Xb. Jing et al., Total synthesis of two neolignans for (+/-)-Eusiderin E and (+/-)-Eusiderin F, CHEM J CH U, 22(1), 2001, pp. 63-66
Citations number
9
Categorie Soggetti
Chemistry
Journal title
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
ISSN journal
02510790 → ACNP
Volume
22
Issue
1
Year of publication
2001
Pages
63 - 66
Database
ISI
SICI code
0251-0790(200101)22:1<63:TSOTNF>2.0.ZU;2-G
Abstract
(+/-)-Eusiderin E and (+/-)-Eusiderin F, two neolignans, were first synthes ized from pyrogallol, in which route the Claisen Rearrangement was used to afford four C6-C3 units 2, 6-dimethoxy-3-allyl-phenol (5), 1-(3, 5-dimethox y-4-hydroxy-phenol) propene(6), 3-methoxy-5-allyl-1, 2-benzene-diol(9), 1-( 5-methoxy-3, 4-dihydroxy-phenol)propene(10).