Predicting the liquid-vapor critical point from the crystal anharmonicity

Authors
Citation
Y. Rosenfeld, Predicting the liquid-vapor critical point from the crystal anharmonicity, CONTR PLASM, 41(2-3), 2001, pp. 183-186
Citations number
18
Categorie Soggetti
Physics
Journal title
CONTRIBUTIONS TO PLASMA PHYSICS
ISSN journal
08631042 → ACNP
Volume
41
Issue
2-3
Year of publication
2001
Pages
183 - 186
Database
ISI
SICI code
0863-1042(2001)41:2-3<183:PTLCPF>2.0.ZU;2-I
Abstract
A 'universal' dependence is predicted of the reduced critical parameters (t emperature, density, and pressure) on the crystal anharmonicity. The model, which employs the 'universal' zero-temperature equation of state in a vers ion of fluid perturbation theory, is apparently the first to predict correc tly the critical temperature and density for both the rare gases and Alkali metals.