Modeling the formation of secondary organic aerosol. 1. Application of theoretical principles to measurements obtained in the alpha-pinene/, beta- pinene/, sabinene/, Delta(3)-carene/, and cyclohexene/ozone systems

Citation
Jf. Pankow et al., Modeling the formation of secondary organic aerosol. 1. Application of theoretical principles to measurements obtained in the alpha-pinene/, beta- pinene/, sabinene/, Delta(3)-carene/, and cyclohexene/ozone systems, ENV SCI TEC, 35(6), 2001, pp. 1164-1172
Citations number
47
Categorie Soggetti
Environment/Ecology,"Environmental Engineering & Energy
Journal title
ENVIRONMENTAL SCIENCE & TECHNOLOGY
ISSN journal
0013936X → ACNP
Volume
35
Issue
6
Year of publication
2001
Pages
1164 - 1172
Database
ISI
SICI code
0013-936X(20010315)35:6<1164:MTFOSO>2.0.ZU;2-2
Abstract
Secondary-organic aerosol (SOA) forms in the atmosphere when volatile paren t compounds are oxidized to form low-volatility products that condense to y ield organic particulate matter (PM). Under conditions of intense photochem ical smog, from 40 to 80% of the particulate organic carbon can be secondar y in origin. Because describing multicomponent condensation requires a comp ound-by-compound identification and quantification of the condensable compo unds, the complexity of ambient SOA has made it difficult to test the abili ty of existing gas/particle (G/P) partitioning theory to predict SOA format ion in urban air. This paper examines that ability using G/P data from past laboratory chamber experiments carried out with five parent hydrocarbons ( HCs) (four monoterpenes at 308 K and cyclohexene at 298 K) in which signifi cant fractions (61-100%) of the total mass of SOA formed from those HCs wer e identified and quantified by compound. The model calculations were based on a matrix representation of the multicomponent, SOA G/P distribution proc ess. The governing equations were solved by an iterative method. Input data for the model included (i) Delta HC (mug m(-3)), the amount of reacted par ent hydrocarbon; (ii) the ci values that give the total concentration T (ga s + partical phase, ng m(-3)) values for each product i according to T-i = 10(3) alpha (i)Delta HC; (iii) estimates of the pure compound liquid vapor pressure p degrees (L) values (at the reaction temperature) for the product s; and (iv) UNIFAC parameters for estimating activity coefficients in the S OA phase for the products as a function of SOA composition. The model predi cts the total amount M-0(mug m-3) of organic aerosol that will form from th e reaction of Delta HC, the total aerosol yield Y(= M-0/Delta HC), and the compound-by-compound yield values Y-i. An impediment in applying the model is the lack of literature data on p(L)degrees values for the compounds of i nterest or even on p(L)degrees values for other, similarly low-volatility c ompounds. This was overcome in part by using the G/P data from the alpha -p inene and cyclohexene experiments to determine p(L)degrees values for use ( along with a set of 14 other independent polar compounds) in calculating UN IFAC vapor pressure parameters that were, in turn, used to estimate all of the needed pe values. The significant degree of resultant circularity in th e calculations for alpha -pinene and cyclohexene helped lead to the good ag reement that was found between the Y-i values predicted by the model, and t hose measured experimentally for those two compounds. However, the model wa s also able to predict the aerosol yield values from beta -pinene, sabinene , and Delta (3)-carene, for which there was significantly less circularity in the calculations, thereby providing evidence supporting the idea that gi ven the correct input information, SOA formation can in fact be accurately modeled as a multicomponent condensation process.