Oxy-fuel combustion has been proven to increase thermal efficiency and to h
ave a potential for NOx emission reduction. The study of 25-kW turbulent di
ffusion flames of natural gas with pure oxygen is undertaken on a coaxial b
urner with quarl. The structural properties are analysed by imaging the ins
tantaneous reaction zone by OH* chemiluminescence and measuring scalar and
velocity profiles. The interaction between the flame front and the shear la
yers present in the coaxial jets depends on the momentum ratio which dictat
es the turbulent structure development. Flame length and NOx emission sensi
tivity to air leaks in the combustion chamber are also investigated.