The synthesis of 2,6,7-trioxa-1,4-diphosphabicyclo[2.2.2]octane revisited:The synthesis of 2,6,7-triphenyl-2N,6N,7N-triaza-1,4-diphosphabicyclo[2.2.2]octane and the synthesis of 1 lambda(5)-phosphiranol

Citation
P. Kisanga et J. Verkade, The synthesis of 2,6,7-trioxa-1,4-diphosphabicyclo[2.2.2]octane revisited:The synthesis of 2,6,7-triphenyl-2N,6N,7N-triaza-1,4-diphosphabicyclo[2.2.2]octane and the synthesis of 1 lambda(5)-phosphiranol, HETEROAT CH, 12(2), 2001, pp. 114-117
Citations number
10
Categorie Soggetti
Chemistry
Journal title
HETEROATOM CHEMISTRY
ISSN journal
10427163 → ACNP
Volume
12
Issue
2
Year of publication
2001
Pages
114 - 117
Database
ISI
SICI code
1042-7163(2001)12:2<114:TSO2R>2.0.ZU;2-9
Abstract
We report herein a reliable synthesis of P(OCH2)(3)P in a stud aimed at und erstanding the factors that control its formation. We also report the seren dipitous synthesis of the novel phosphiranol (CH2)(2)PO2H and the synthesis of P(PhNCH2)(3)P in good yield. (C) 2001 John Wiley & Sons, Inc.