Two new hydrolyzable tannins, nobotanin S (1) and melastoflorin A (2), were
isolated from the leaves of Monochaetum multiflorum, and their structures
were characterized as tetrameric and pentameric ellagitannins based on deta
iled NMR analyses using 2D-NMR techniques and chemical evidence. Melastoflo
rin A (pentamer) was notably the biggest molecule among numerous hydrolyzab
le tannins.