Synthesis and characterization of lanthanide(III) complexes of beta-benzoyl and alpha-phenyl-beta-benzoyl propionic acids

Citation
C. Meenakshi et al., Synthesis and characterization of lanthanide(III) complexes of beta-benzoyl and alpha-phenyl-beta-benzoyl propionic acids, I J CHEM A, 40(2), 2001, pp. 207-210
Citations number
7
Categorie Soggetti
Chemistry
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY
ISSN journal
03764710 → ACNP
Volume
40
Issue
2
Year of publication
2001
Pages
207 - 210
Database
ISI
SICI code
0376-4710(200102)40:2<207:SACOLC>2.0.ZU;2-Z
Abstract
Synthesis and characterization of lanthanum(III), prasrodymium(III), neodym ium(III), samarium(III), godolinium(III), terbium(III), and dysprosium(III) chelates of the type of M{(RCOO)(3)} 2H(2)O where R=PhCOCH2CH2 and PhCOCH2 CHPh are described. The IR data show that the bonding of the carboxylate gr oup to the metal ion is bidendate chelate mode. Coordination number of 6 In d 9 is suggested for the rare earth ion in these two series respectively.