Citation
Vk. Jain et al., Preparation and characterization of platinacycloalkanes containing nitrogen donor ligands, I J CHEM A, 39(9), 2000, pp. 974-979
Citations number
20
Categorie Soggetti
Chemistry
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY
ISSN journal
03764710
→ ACNP
Volume
39
Issue
9
Year of publication
2000
Pages
974 - 979
Database
ISI
SICI code
0376-4710(200009)39:9<974:PACOPC>2.0.ZU;2-F
Abstract
[PtCl2(C3H5Me)(NN)] (where X = Cl, I; n = 3 or 4; NN = bis(1-pyrazolyl) met
hane, bis(3,5-dimethyl-1-pyrazolyl) methane, bis (2-pyridyl) methane and 2,
2 ' -bipyridyl) have been prepared and characterized by elemental analyses,
IR,H-1 and C-13 NMR spectroscopy. The compounds [PtCl2(C3H5Me(NN)] exist a
s mixtures of 2- and 3- methyl platinacyclobutane isomers. In solution thes
e compounds possess an octahedral geometry in which halo groups occupy the
axial positions.