[K(18C6)](2)[Pt(SCN)(4)](H2O): A novel one-dimensional coordination polymer with K-N bonds

Authors
Liu, Y Dou, JM Zhu, LY Sun, DZ Zheng, PJ
Citation
Y. Liu et al., [K(18C6)](2)[Pt(SCN)(4)](H2O): A novel one-dimensional coordination polymer with K-N bonds, I J CHEM A, 39(9), 2000, pp. 983-984
Citations number
16
Categorie Soggetti
Chemistry
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY
ISSN journal
03764710 → ACNP
Volume
39
Issue
9
Year of publication
2000
Pages
983 - 984
Database
ISI
SICI code
0376-4710(200009)39:9<983:[ANOCP>2.0.ZU;2-1
Abstract
Pt(II) 18-crown-6 complex [K(18C6)](2)[Pt(SCN)(4)](H2O) has been isolated a nd characterized by X-ray diffraction analysis. The crystal structure belon gs to monoclinic, space group P2(1)/n with cell dimensions, a = 1.1116(1), b = 1.2258(1), c = 1.5856(1) nm, beta = 93.479(9)degrees, V= 2.1567(3) nm(3 ), Z = 2, R = 0.033 and Rw = 0.051. In the solid state, the complex display s a one-dimensional infinite chain of two [K(18C6)](+) complex cations and a [Pt(SCN)(4)](2-) anion bridged by one H2O molecule between adjacent [K(18 C6)](+) units.