Synthesis and structure of the copper(I) complex - [Cu(dppm) (2,2 '-bipy)](2)(NO3)(2)

Authors
Wang, DM Yang, RN Hou, YM Hu, XY Jin, DM
Citation
Dm. Wang et al., Synthesis and structure of the copper(I) complex - [Cu(dppm) (2,2 '-bipy)](2)(NO3)(2), I J CHEM A, 39(9), 2000, pp. 985-988
Citations number
11
Categorie Soggetti
Chemistry
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY
ISSN journal
03764710 → ACNP
Volume
39
Issue
9
Year of publication
2000
Pages
985 - 988
Database
ISI
SICI code
0376-4710(200009)39:9<985:SASOTC>2.0.ZU;2-P
Abstract
Binuclear copper(I) complex [Cu(dppm)(2,2 ' -biPY)](2)(NO3)(2) (1), dppm=Ph 2PCH2PPh2] has been synthesized by a ligand replacement reaction. X-ray cry stal structure of the complex (1) shows that dppm coordinates as a bridging bidentate ligand, and 2,2 ' -bipy as a bidentate ligand to the Cu(I) atoms with tetrahedral structure. NO3- behaves as a free ion in this newly prepa red binuclear copper(I) complex. Crystals (1) are monoclinic P2(1)/n, a = 1 .4663(5); b = 1.3076(5), c = 1.9910(6) nm; beta =110.66(3)degrees, V = 3.57 19 nm(3), Z = 2, F(000) =1536, Dc= 1.332 g cm(-3) 0.06320, Rw = 0.08132.