Synthesis and spectral studies of oxomolybdenum(V) and dioxomolybdenum(VI)complexes of 1,2-dihydro-1,5-dimethyl-2-phenyl-4-(2,4-dihydroxyphenylazo)-3-H-pyrazol-3-one

Authors
Nair, MLH Prabhakaran, CP
Citation
Mlh. Nair et Cp. Prabhakaran, Synthesis and spectral studies of oxomolybdenum(V) and dioxomolybdenum(VI)complexes of 1,2-dihydro-1,5-dimethyl-2-phenyl-4-(2,4-dihydroxyphenylazo)-3-H-pyrazol-3-one, I J CHEM A, 39(9), 2000, pp. 989-992
Citations number
17
Categorie Soggetti
Chemistry
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY
ISSN journal
03764710 → ACNP
Volume
39
Issue
9
Year of publication
2000
Pages
989 - 992
Database
ISI
SICI code
0376-4710(200009)39:9<989:SASSOO>2.0.ZU;2-F
Abstract
A few oxomolybdenum(V) complexes of the formulae [MoO(RAAP)Cl-2], [MoO(RAAP )Br-2], [MoO(RAAP)(NCS)Cl], [MoO(RAAP)(NO3)Cl], [MoO(RAAPH)(2)Cl](Clo(4))(2 ), and dioxo molybdenum(VI) complexes of the formulae [MoO2 (RAAPH) (NCS)Cl ], [MoO2(RAAPH)(NO3)Cl] and [MoO2 (RAAPH)(2)Cl] (ClO4) (where RAAPH resorci nolazoantipyrine) have been synthesised and characterised by elemental anal ysis, IR, electronic, ESR, magnetic and conductance measurements. The X-ray powder diffraction pattern of one of the complexes has also been examined.