Molybdenum(V) complexes of dithiocarbonates derived from glucose, sucrose and triphenylmethylcarbinol

Authors
Mohandoss, K Nagaraja, KS
Citation
K. Mohandoss et Ks. Nagaraja, Molybdenum(V) complexes of dithiocarbonates derived from glucose, sucrose and triphenylmethylcarbinol, I J CHEM A, 39(10), 2000, pp. 1083-1086
Citations number
20
Categorie Soggetti
Chemistry
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY
ISSN journal
03764710 → ACNP
Volume
39
Issue
10
Year of publication
2000
Pages
1083 - 1086
Database
ISI
SICI code
0376-4710(200010)39:10<1083:MCODDF>2.0.ZU;2-Z
Abstract
D-Glucose, sucrose and triphenylmethylcarbinol dithiocarbonate complexes of molybdenum(V), [Mo2OS3(glu-2CS(2))]. 2H(2)O, [Mo2S4(suc-4CS(2))]. 2H(2)O, and [Mo2OS3(Ph3COCS2)(2)]. 2H(2)O, respectively have been synthesized. The compositions are strongly influenced by the nature of xanthates and the exp erimental conditions of preparation. The TG-DTA data suggest the presence o f lattice water. On the basis of magnetic moment and spectroscopic data, ox o or sulphido bridged structures are suggested for the molybdenum compounds .