Spectrophotometric determination of vanadium(V) using methdilazine hydrochloride in minerals and steel samples

Authors
Melwanki, MB Seetharamappa, J
Citation
Mb. Melwanki et J. Seetharamappa, Spectrophotometric determination of vanadium(V) using methdilazine hydrochloride in minerals and steel samples, I J CHEM A, 39(10), 2000, pp. 1107-1109
Citations number
10
Categorie Soggetti
Chemistry
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY
ISSN journal
03764710 → ACNP
Volume
39
Issue
10
Year of publication
2000
Pages
1107 - 1109
Database
ISI
SICI code
0376-4710(200010)39:10<1107:SDOVUM>2.0.ZU;2-R
Abstract
Methdilazine hydrochloride has been used as a sensitive and selective reage nt for the rapid spectrophotometric determination of vanadium(V). The reage nt gives instantaneously a red coloured species on reaction with vanadium(V ) in phosphoric acid medium and exhibits maximum absorbance at 512 nm with Sandell's sensitivity of 6.72 ng cm(-2). Beer's law is obeyed over the conc entration range 0.2-5.4 ppm; the optimum concentration range is 0.5-5.0 ppm . The method has been successfully applied to the analysis of vanadium stee ls and minerals.