Semiconductor properties in an iodine-doped platinum(II) dinuclear complex

Authors
DeRosa, MC Al-mutlaq, F Crutchley, RJ
Citation
Mc. Derosa et al., Semiconductor properties in an iodine-doped platinum(II) dinuclear complex, INORG CHEM, 40(7), 2001, pp. 1406
Citations number
15
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
40
Issue
7
Year of publication
2001
Database
ISI
SICI code
0020-1669(20010326)40:7<1406:SPIAIP>2.0.ZU;2-Y
Abstract
The complex [{Pt(trpy)}(2)(mu -Me(2)dicyd)] [PF6](2), where trpy is 2,2':6' ,2"-terpyridine and Me(2)dicyd(2-) is 2,5-dimethyl-1,4-dicyanamidebenzene d ianion, has been synthesized. Upon doping with iodine, conductivity maxima occur at stoichiometries of [{Pt(trpy)}(2)(mu -Me-2-dicyd)][PF6](2). [I-3]( x) of x = 0.8 (sigma = 8 muS cm(-1)) and 1.3 (a = 39 muS cm(-1)). [GRAPHICS]