Cation templation of anionic metal dicyanamide networks

Authors
van der Werff, PM Batten, SR Jensen, P Moubaraki, B Murray, KS
Citation
Pm. Van Der Werff et al., Cation templation of anionic metal dicyanamide networks, INORG CHEM, 40(7), 2001, pp. 1718
Citations number
40
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
40
Issue
7
Year of publication
2001
Database
ISI
SICI code
0020-1669(20010326)40:7<1718:CTOAMD>2.0.ZU;2-J
Abstract
The dimensionality and topology of anionic M(dca)(3)(-) networks (dca = dic yanamide, N(CN)(2)(-)) are templated by the countercations included in the network. 2D structures result with Ph4E+, E = P, As cations (see picture, w hile 3D structures result from use of MePh3P+ cations. Magnetic measurement s on M = Mn-II show that very weak antiferromagnetic coupling occurs in the 2D and 3D systems resulting in J values of ca. -0.1 cm(-1). [GRAPHICS]