ENANTIOSELECTIVE SYNTHESIS OF THE WHITE KEY INTERMEDIATE FOR THE SYNTHESIS OF TRISPORIC ACIDS

Authors
BACIGALUPPO JA COLOMBO MI CRAVERO RM GONZALEZSIERRA M PREITE MD ZINCZUK J RUVEDA EA
Citation
Ja. Bacigaluppo et al., ENANTIOSELECTIVE SYNTHESIS OF THE WHITE KEY INTERMEDIATE FOR THE SYNTHESIS OF TRISPORIC ACIDS, Tetrahedron : asymmetry, 5(10), 1994, pp. 1877-1880
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
5
Issue
10
Year of publication
1994
Pages
1877 - 1880
Database
ISI
SICI code
0957-4166(1994)5:10<1877:ESOTWK>2.0.ZU;2-L
Abstract
The asymmetric construction of the alkylated cyclohexenone carboxylic acid moiety of trisporic acids A, B and C and the syntheses of related precursors are described. The syntheses feature a Michael addition in tandem with an aldol condensation as the central step.