Metal K beta X-ray emission spectra of first row transition metal compounds

Authors
Gamblin, SD Urch, DS
Citation
Sd. Gamblin et Ds. Urch, Metal K beta X-ray emission spectra of first row transition metal compounds, J ELEC SPEC, 113(2-3), 2001, pp. 179-192
Citations number
27
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA
ISSN journal
03682048 → ACNP
Volume
113
Issue
2-3
Year of publication
2001
Pages
179 - 192
Database
ISI
SICI code
0368-2048(200102)113:2-3<179:MKBXES>2.0.ZU;2-2
Abstract
A large body of first row transition K beta X-ray emission spectra are pres ented and the splitting of the K beta peak into K beta ' and K beta (1,3) i s quantified by a consistent curvefitting procedure. Broad trends in the K beta ' :K beta (1,3) intensity ratio are identified and related to the oxid ation state of the metal and its chemical environment. Implications for the development of X-ray emission spectroscopy as a tool for chemical speciati on are considered. (C) 2001 Elsevier Science B.V. All rights reserved.