This study represents a facile synthesis of building blocks (1-3) of crown
ethers and amine precoursers (4a-d). The study also involves synthesis of m
ono and dibenzo N,N'-disubstituted diaza 18-crown-6 derivatives with high y
ield without chromatographic purification and high vacuum distillation. The
complex ability of host the ethers was evaluated in terms of structural mo
dification.