Ilmenite as a source for zirconium during high-grade metamorphism? Textural evidence from the Caledonides of western Norway and implications for zircon geochronology
B. Bingen et al., Ilmenite as a source for zirconium during high-grade metamorphism? Textural evidence from the Caledonides of western Norway and implications for zircon geochronology, J PETROLOGY, 42(2), 2001, pp. 355-375
The Proterozoic Lindas Nappe, part of the Caledonides of western Norway, wa
s affected by penetrative Sveconorwegian granulite-facies metamorphism,foll
owed by a fluid-driven eclogite- and amphibolite-facies Caledonian overprin
t, spatially restricted along fractures and shear zones. In mafic granulite
s and amphibolites, a luminescent anhedral zircon overgrowth, which gives a
n average age of 924 +/- 58 Ma (Th/U = 0(.)52; secondary ion mass spectrome
try data), surrounds a magmatic toned core with an age of 952 +/- 32 Ma (Th
/U = 1(.)27). In the granulites, a continuous rim of zircon or a discontinu
ous corona of similar to 10 mum rounded ta flat zircon crystals is observed
at the outer margin of ilmenite grains. Baddeleyite and srilankite (Ti2ZrO
6) blebs are reported around ilmenite included in feldspar or pyroxene. Bad
deleyite is interpreted as an exsolution product from magmatic ilmenite, wh
ereas srilankite, the zircon corona around ilmenite and the luminescent zir
con overgrowth were fanned as reaction products during granulite;facies met
amorphism. Textures suggest that magmatic ilmenite war a main source of Zr
to form metamorphic zircon. In massive amphibolites, relic ilmenite grains
are surrounded by a corona of titanite and a discontinuous corona of micro-
zircons. Amphibolite-facies overprint is not associated with any significan
t growth or dissolution of zircon. An unsheared eclogite displays a zircon
population with a euhedral oscillatory zoned overgrowth giving an age of 45
5 +/- 29 Ma (Th/U less than or equal to 0(.)13). A corona of micro- zircon
grains is observed at same distance around rutile, and locally these zircon
s show a prismatic overgrowth. A specific low-Th zircon growth event is rel
ated to eclogite-facies forming reactions, involving breakdown of a two pyr
oxene + garnet + plagioclase + ilmenite assemblage to form a garnet + ompha
cite + rutile assemblage in the presence of a fluid. The low Th content of
this zircon probably stems from the coeval Precipitation of clinozoisite. T
his oscillatory toned zircon records fluid infiltration and coeval eclogiti
zation in the dust.